Would the ML 326s be worth the extra 2 grand or so ?
Only you can make that decision.
I am sure that you will be happy with either one though.
I would think that if you are paying an extra 2 grand, the price is either really good on the ARC Ref 3, or really bad on the 326S.
I see them selling for about the same price, unless the 326S has the optional phono stage, and even then it's only about $600-$1,000 more.
Now that is judging by sold prices on HiFiShark, not asking prices in current ads.
So if you are seeing a 2 grand difference, either the asking price for the 326S is too high, or the asking price for the Ref 3 is too low.