I own a very nice amp with silver wire output transformers--Audio Note Kageki. But, I cannot say that it is necessarily the transformer wire composition that makes it a very good amp. I also own a pushpull amp with copper wiring that I actually prefer to the Kageki (a custom made clone of a Western Electric 133). The two best amps I've heard did not have silver transformers; one is the Western Electric 59a, and the other is a custom-made OTL amp that doesn't have output transformers.
I don't think that any particular design feature is the be-all and end-all of amplifier design.
I don't think that any particular design feature is the be-all and end-all of amplifier design.