And you determined these amps that you were listening to were clipping how, exactly? I constantly hear this stuff on these groups, hard vs soft clipping, even vs odd harmonics, class A vs class AB, tubes are valves and transisters are switches, etc.
You want to know why tube amps sound different than SS amps? All you have to do is look at the frequency response graphs published in every Stereophile review and look at the trace using the simulated speaker load. The amplifier's output impedance is basically in series with the speaker load. A tube amp's impedance is so high that it creates a divider network consisting of itself and the speaker load.
Tubes - Big humps at 65-70 HZ and 1.5 KHZ, big dips in the mid bass and treble, dropping sharply after 10 KHZ.
SS - Flat.