Certain assumptions are being used to justify finding brass or any other material inferior without the assumptions being supported. Is conductivity the deciding factor in what sounds good? Is it necessarily the case that a material that that reduces conductivity or in any other aspect alters the signal necessarily bad for the sound? So much is being made about the particular connector's, or for that matter the cable itself, physical properties under the assumption that there is a set of properties which, if optimized, will always result in superior sound. It does not work that way because each system is different and each listener has sound preferences that may mean different alterations to the signal will either be desired or deleterious.
Does it matter if Tara uses gold plated brass? Yes and no. If it alters the sound as compared to some other choice, it matters but one cannot say for the better or worse on a universal basis. If it doesn't alter the sound in any system, then cheaper or more durable is desirable.
i don't care what material is used for the connectors in my cable (Audio Note silver wire); I care about the sound of the cable as a whole. I looked it up because of this thread and found out that my banana terminated cables utilize silver over what I will call "mystery metal" (the description is only that it is non-magnetic material) for the connectors.