Setting up a truly objective blind test (one that eliminates all of the biases that scientists claim are inherent in sighted comparisons) is not a trivial matter. Plus, you need at least a smattering of statistics training to properly interpret the results. That makes true blind testing a nonstarter for most audiophiles. And this being just a hobby, there's no need for that kind of rigor.
One important thing to remember is that blind tests can prove there's a difference, but they cannot prove that there isn't, or that you can't hear one. That's a basic law of statistics. (On the other hand, if you do a whole lot of blind tests that come up negative, the evidence does start to point in a certain direction...)
That said, if you're interested in the limits of what humans can and cannot hear, and why blind testing is essential in determining this, you should pick up a basic text in psychoacoustics. Used, older editions can be had cheaply, and it might save you some money on audio gear.
One important thing to remember is that blind tests can prove there's a difference, but they cannot prove that there isn't, or that you can't hear one. That's a basic law of statistics. (On the other hand, if you do a whole lot of blind tests that come up negative, the evidence does start to point in a certain direction...)
That said, if you're interested in the limits of what humans can and cannot hear, and why blind testing is essential in determining this, you should pick up a basic text in psychoacoustics. Used, older editions can be had cheaply, and it might save you some money on audio gear.