Unique female voices always get my attention. Some modern finds.....
Yukimi Nagano of the Swedish band Little Dragon. A great sample here:
http://www.youtube.com/watch?v=tcP5ivpLbCM
She is just as good live. Little Dragon is great actually.
Yukimi lends her voice to a few other projects and jazz bands as well, including Koop and Sleep Walker
Another very unique and new to me performer, is Elsieanne Caplette of Elsiane. http://www.myspace.com/elsiane
Cool thread. I will check out the other suggestions.