Monoblocks will normally have much bigger power supplies and are usually fully balanced/differential on the amplifier output stage. Stereo amps do not normally have balanced/differential output stages, but there are definitely exceptions.
The Pass Labs could be fully balanced/differential, even though they are stereo (I know of at least one post, possibly by Bob Reynolds, that indicates a Pass Labs stereo was differential on the output). That being said, either the 250.8 or the 350.8 will most likely wipe the floor with the Emotiva amps, so I wouldn't worry that these are stereo or lower power rating. Check out the following thread:
https://forum.audiogon.com/discussions/my-long-list-of-amplifiers-and-my-personal-review-of-each
He does a massive list of amps and descriptions of their sonic signature. As far as the thread goes, the Pass ".8" models are near the top of the line.
I would not bi-amp the speakers using the extra "bi-amp outputs" on the 8802a. This never works out best anyways. The Marantz processor (and any other processor) will send higher frequencies to the upper bi-amp output by comparing the used frequencies of the main output and subtracting them from the full-range signal. This results in lost resolution and the sound is just soft and not impactful. Better way to bi-amp is just to use a Y-splitter cable, but then you are messing with combining two amplifier input impedances and you may lose sound quality this way. It's better just to run an amplifier full-range to a speaker. Bi-wire is good to reduce the speaker cable resistance.