Echolane, I'm having a difficult time envisioning how all the components in your system are being swapped out and interacting without first drawing a massive diagram on my wall ; )
Let's go back to David's point about the differences between the two Oppos. Do you still have the 83 so that you can see how it works with the Pioneer? And secondly, is there a standalone DAC anywhere in your system, or is/was everything played through one of the Oppos? If you don't have a standalone DAC, then the Oppo switch is a major sonic change for your system and could very well be the source of the brightness. For a DAC, I use a Metrum Onyx and before that an MHDT Havana, both of which are non-oversampling, since my ears are very prickly in response to to certain types of digital processing. If you do isolate the Oppo as the problem area, then you might want to consider a good power cable rather than the stock one and then swap in some smooth ICs for your preamp and amps.
Let's go back to David's point about the differences between the two Oppos. Do you still have the 83 so that you can see how it works with the Pioneer? And secondly, is there a standalone DAC anywhere in your system, or is/was everything played through one of the Oppos? If you don't have a standalone DAC, then the Oppo switch is a major sonic change for your system and could very well be the source of the brightness. For a DAC, I use a Metrum Onyx and before that an MHDT Havana, both of which are non-oversampling, since my ears are very prickly in response to to certain types of digital processing. If you do isolate the Oppo as the problem area, then you might want to consider a good power cable rather than the stock one and then swap in some smooth ICs for your preamp and amps.