I have Mofi, Reference Recordings, Shefield Labs, Impex, AP, Blue Note, Mercury Living Presence, and most of the other labels. In addition to standard 33&1/3, I have 45 rpm, 1/2 speed master, 1-Step, and even a single-sided 4-disc set from Classic (Nora Jones, Come Away With Me)
For straight SQ, the winner air my VTL LPs, a.) Doctor, b.) Josh. The best 'value' high SQ label is Windham Hill (1/2 speed master by Stan Ricker, Bernie G., etc.) I listen to one of them most evenings.
Also, @ tubes4good mentioned 'anything on Chesky'. My Chesky LPs are excellent (~10, or so), but I would give the upper SQ-hand to Harmonia Mundi (the original French records, not the BASF French-German records, which are a step lower in SQ).
You pick, and happy listening...