kalali---For one thing, the tape out jacks are fixed in level, not variable like the mains, so they can’t be used to feed a power amp (unless your amp has level pots). Also, they are taken from before the final stage of amplification in a pre, and their output impedance is often different from that of the mains.
But as cleeds said, those outputs are also used as the source for digital recorders, as well as surround sound processors and digital room correction devices (DSPeaker Anti-Mode, for instance).