coop_301
I have a RME ADI-2 Pro AE powered by a LPS and have tried what you are asking. My system is Bryston/Thiel. RME (with digital volume control disabled by locking it at 0dB) connected to preamp sounds much better than RME (with digital volume control active) directly connected to power amp.
I have extensively tested the audibility of the RME digital volume control and can assure you it significantly degrades the sound quality, no matter what RME’s designer claims. But even with the digital volume control disabled, I think the RME is too far below the level of your ML/Thiel. A true high-end DAC should nail you to the listening chair until the track finishes. It does not do it for me - I just use it as a headphone DAC/amp for my PC/video editing setup. It is good for the price but is no giant killer.
Best wishes.