Glai,
You'll certainly see/learn something with the microscope. It should help you find a "close approximate starting point". Don_c55's statement that 80% of all LP's were cut at precisely 92 degrees is not consistent with my experience, but my collection extends from very early LP's from before 1955 to current releases, 4000 LP's on dozens of record labels. If a collection were limited to recent releases I'd agree with him.
Of course within reason it really doesn't much matter where you start. What matters is where you finish. :-)
Suggestions:
First, please start thinking about SRA, not VTA. They are two different things. What you'll be viewing with your microscope is SRA. The changes you'll hear as your listening skills advance will be primarily due to changes in SRA, only secondarily to changes in VTA.
Skipping over the correct SRA setting is very easy because the window is very small. This is especially true with modern line contact or micro-ridge stylus profiles. Until you become practiced it's helpful to hunt in very tiny increments, no more than 5 points on the TriPlanar's 100 point dial for example. Our recorded height settings on about 1000 LP's are to the nearest 1/2 point on that dial (1/200th of a turn). If you crank the dial around in big moves you'll skip right by and not know it, especially if you're not attuned to what to listen for.
P.S. With the TP or any threaded adjuster, don't forget to always approach the desired setting from below, which takes up the backlash in the threads. Otherwise you'll just have chaos.
What to listen for?
Frank Schroeder describes it as "the integration of fundamental and harmonics across the time domain". What????? Actually that's a perfect description. (FWIW, in less resolving setups you'll hear a shift in perceived frequency balance, but that's due to system-induced mud. Your system appears to be more resolving than that.)
Every note from a real, acoustic instrument is composed of a fundamental plus higher order harmonics. If the arm base is too high, you'll hear the higher frequency harmonics BEFORE the fundamental. The ring and hiss off a cymbal begin before the actual tap. (In that less resolving system it'll just sound "bright".) If the arm base is too low, you'll hear the fundamental followed by an unnatural time lag before the harmonics. (In that less resolving system it'll just sound bass-heavy.) When SRA is just right, the tap and the resulting harmonics will be tight and properly integrated in the TIME domain, as Frank said. (I heard all this before I heard Frank offer that description, but I can't think of a better or more succinct one.)
Remember, all this change happens in that very narrow adjustment window, 1/2 a turn of the TP's dial or less. If you're outside the window you may not hear anything at all from a height change. Work patiently.
As to particular records, forget any amplified instruments or anything with added reverb. Both of those totally screw up time domain information. Acoustic instruments, well and naturally recorded, are the best for building listening skills. Notes with clear leading transients are easier than sustained tones (adjusting SRA using a sustained organ or flute note is almost impossible). Vocals are possible to use if they contain lots of voiced fricatives and explosives (S's, T's, D's, K's, hard G's, etc.). No one can set SRA from "la-la-la".
It's pointless being more specific because different ears react differently, though they should lead to the same result.
Example:
I hear SRA changes best in higher pitched instruments with quick transients and a good decay. Plucked string instruments of any type, cymbal taps, etc. My partner hears SRA best in low frequency instruments. Despite this difference in what we're most sensitive to, we invariably agree on the best setting. Not knowing how your ears work (even you don't, yet!) I suggest focusing on different sounds until they "get" it.
Now get to work! :-)