Seriously?? Head azimuth **is** part of head alignment! Along with head height (on reel to reels). On a cassette deck azimuth is the only adjustment you get when aligning the heads. So on cassettes, azimuth and head alignment are exactly the same thing.
The reason I bring up cassette is that it’s a lot more annoying to make adjustments than on reel to reel, mostly you can’t trust cassettes to give you reliable results because the azimuth is always changing. Even if you adjust to a standard there will never be a correct azimuth when it comes to cassettes even on the best three heads decks. For that reason performance will always be lackluster unless you are making your own recordings. A good example are tapes recorded on Nak decks notoriously sound bad on non-Nak decks. On the other hand you would like to believe that reel to reel will give you more accurate results, but that too is not always the case.
http://www.tapeheads.net/showthread.php?t=70517
The best way I can describe it is this. The azimuth I refer to is what is printed on the tape in response to the record head. No one machine will have the same azimuth and no one tape will have the same azimuth. I bring this up to point out the performance of reel to reel will give you significantly better results than any cassette deck. Not because of the speed. Using the example of speed, 1⅞ ips can sound just as good at 15 ips except one will have more tape hiss. The difference is that reel to reel will always have greater frequency response because of the nature of its azimuth. The way the playback head is being used allows you to pull more information out of it.
Anyhow that has given me the best results so far listening back and fourth. That is how I squeeze the most information out of every tape that comes into my possession. I do not calibrate the machines I use in my lineup. Personal preference.