Each 10degC temp increase shortens capacitor life by 2. It is simply drying out of electrolyte. Drier capacitors have higher ESR. At certain point current thru capacitors causes internal temperature increase. Temperature increases ESR and higher ESR increases power dissipated inside increasing temperature further. It is Avalanche effect that can cause explosion. To prevent serious damage all electrolytic caps have some form of pressure relief - either rubber plug or cross cut that weakens one side. Hot capacitors should be replaced as soon as possible.