Which model QNAP and how much RAM does it have versus the PC? You changed your server from a pc with (assuming) and Intel or AMD cpu to an albeit streamlined linux box with an (assuming) Arm processor. As odd as it sounds, that can make a huge difference in sound quality, as least in my system.
I, too, use a Logitech streamer, albeit the Transporter, and can easily hear differences between servers, especially if using any DSP or upsampling in software on the server. Just my two cents...maybe switch servers while keeping the Cambridge and see what differences you hear??