I don't know how the DD-12 works, but I presume it has a separe line level input and speaker level input and the EQ and Xover can only be applied to the line level input - I could be completely wrong on this. If this is the case you cannot use the speaker level input, because your subs would run on a full range signal, which would be a complete mess with your mains.
I also would personally never run my mains with a high pass signal out of a relatively low grade Xover build into the sub. (not to mention long runs of cabling from preamp to cabling back into your main power amp.
So to me the only option would be to split the line level signal from the preamp and run parallel into mains and sub, applying EQ in the sub and using the sub xover for low pass filtering. If there are no impedance issues with this approach this would be preferable IMO. Of course, you run your mains at full range in this setup. In my (limited) experience this is not an issue, as long as you use a low crossover point for your subs.
I also would personally never run my mains with a high pass signal out of a relatively low grade Xover build into the sub. (not to mention long runs of cabling from preamp to cabling back into your main power amp.
So to me the only option would be to split the line level signal from the preamp and run parallel into mains and sub, applying EQ in the sub and using the sub xover for low pass filtering. If there are no impedance issues with this approach this would be preferable IMO. Of course, you run your mains at full range in this setup. In my (limited) experience this is not an issue, as long as you use a low crossover point for your subs.