Copper is more conductive than gold. If you're worried about tarnishing, put a thin layer of silicone grease on the bare copper surface. But will you hear a difference? Does it matter that you have a pure copper spade with no plating if the jack is nickel plated? Let's assume even the jack is bare copper, will it matter while the leads of any resistors or capacitors in the signal path are a tinned metal inferior to bare copper? Will it matter if you have pure silver speaker wire if the interconnects leading to the inputs of your amp are copper running through plated brass jacks, which are fed by copper traces on a printed circuit board? Honestly, where do you draw the line if you're going to chase nonsensical things like this?
There are bigger fish to try, such as upgrading to better quality electronic components within your current equipment.