It makes sense no pre would be most transparent, resolving, the straight wire concept.
Go back earlier in this thread to see what a straight wire isn't always the most neutral. The problem is that a passive volume control isn't a bit of wire. If it were, it would not have a resistance value.
Math and engineering principles are at play here- when you put a resistance in series with a source impedance which is expected to drive something to the best of its ability, its rarely a good thing. This can cause an audible and measurable loss of bass and impact. Put simply, its an example of a thing that is too simple to to its task properly.
This is not to say that you can't get it to work. To do that you have to be sure that your source has a direct coupled output and is capable of driving the load (the input of the amplifier) properly. And the interconnect cables will have to be kept short, and RCA only (balanced lines can't be executed with a passive volume control and observing the balanced line standard at the same time).