You may never connect the active outputs of an amplifier together. Even a tiny voltage difference can cause large and damaging current flows.
What you can do is bi-amp a speaker which has two separate binding posts IF the binding posts themselves are not internally connected.
If your amplifier is fully balanced AND you want to bi-amp a speaker you must check that there’s no continuity between speaker grounds or hots. For most amps just making sure the hots have infinite impedance is enough.