Yes, room treatment it is a science. Do yourself a huge favor, and download REW software and learn how to use it and interpret the data. Start by optimizing the position of your speakers and listening position, then begin to add treatments addressing first reflection points, slap echo etc. Sometimes, you can get surprising improvements by careful positioning of room treatments other than the listening position.
You can do a certain amount without measuring, but it can be slow progress. Most of us can discern small differences for the better or worse by ear. But after a while, it can get to be mind boggling to keep track of. There are so many variables. I like graphs that I can archive along with notes on listening impressions associated with a given room configuration. I can tell you my room is orders of magnitude better than when I started, and I never would have gotten where I am now without REW. If you invest a little time and effort you won't be sorry.
You can do a certain amount without measuring, but it can be slow progress. Most of us can discern small differences for the better or worse by ear. But after a while, it can get to be mind boggling to keep track of. There are so many variables. I like graphs that I can archive along with notes on listening impressions associated with a given room configuration. I can tell you my room is orders of magnitude better than when I started, and I never would have gotten where I am now without REW. If you invest a little time and effort you won't be sorry.