I don't know what a "power envelope" is, but the difference between class "A" and "B" is how the signal is split when it is amplified.
In a class A amplifier, the entire signal, split into parts, + and -, is run through two identical amplifying circuits that do NOT split the signal at all. The whole signal is put through a transistor group, but it is never split into smaller components.
In a class B amplifier, the signal is split in two, which are in phase. There are now four amplifying circuits, two for both + and -. It is then recombined after amplification, and put across the binding posts.
Both of these have their advantages and disadvantages. Class A is the purists method. The signal is never tampered with, so it will remain cleaner. Class B splits the signal and then recombines it, which can create crossover distortion. But in a class A amp, the transitors are made to be driven much harder, which generates more heat. The transistors in a class B design do not have to be run at such high gain levels, which in turn allows them to run cooler.
A class "A/B" amp is simply one that runs class "A" up to a certain power level, where the amp switches from A to B operation, allowing for lower heat levels. The catch is that most A/B amps set the power level of this switching very low, making the amp, in essence, a class B amp (unless one is using high-sensitivity speakers). Hope this helps. Cheers!