It's hard to believe that the tubes would limit HF response...after all tubes are (or were) used for RF amplification. In a tube power amp the output transformer is the component that limits HF response, and a large amount of feedback around the transformer (often provided by dedicated windings connected to secondary grids of the output tubes) is necessary to provide flat response over the generally-accepted audio range. If your amp is a "low feedback" design the trade-off is limited frequency response.
Also, why not try a supertweeter? It could be your speakers. Or your ageing ears.
Also, why not try a supertweeter? It could be your speakers. Or your ageing ears.