What capacitor values?

If you like the sound: Leave it as is! You've no one to please but yourself. Based on the impedances you gave, the values/points/slopes should be as noted. I was suggesting what generally works well for x-over points. Especially with a 12"/5 1/4"/and tweeter. Happy experimenting/listening!

One final question Rodman,
If I change the cap value on the Mid/Woofer from 10uF to 40uF, what is the possible risk/downside as your best guess?

Mr H- No risk at all. It would bring the mid in at about 1kHz which is probably closer to the the neighborhood of the 12's natural roll-off. See if you can find the data on your 12". Often that will supply you with a freq response plot. Check it's 3db down point(upper) and design accordingly, if you don't want to use an inductor.

And a 3.5uF on top should bring the tweeter in about 7500Hz.
Is this OK do you think or should I be aiming for lower than this?

I'm not certain of the response of your midrange, never having seen the data. BUT- Most don't operate smoothly up to 7500Hz. If you look at this response: (http://www.madisound.com/catalog/PDF/scanspeak/12m_4631g00e.pdf) You'll note how erratic the response becomes after 5k. In the case of this mid: I would use it between about 700 and 5kHz where it's response is the smoothest. You may be able to find data for your particular driver, and choose roll-off points accordingly. On the other hand: Most tweeters are designed to function smoothly from somewhat below 5k to above(what's generally considered) audibilty.