DTC:
I am only using dB Poweramp which has limited file processing capabilities. Thanks for the suggestion for Vinyl Studio, as I would like software to "crop" lead in and lead out noise and song transitions. I would stay away from those pop and tick removers because they may be altering the sound data.
I have not directly compared 24/96K vs 24/192K, although I have read in some forums that 24/96K is the best sonically. This was confirmed by the Tech at Benchmark (sorry I cannot remember his name). The explanation had something to do with the anti-aliasing filters and digital processing...not my cup of tea. Plus, the 96K files are half the size so that is a plus when recording to flashcards. But to each his own and if you feel the 192K is more "accurate" then by all means, use it.
I do like the volume normalize function in dBpoweramp that lets you convert the file data to 32 bit floating point, perform all the math in floating point, then re-convert back to 24 bit.
Regarding writing to the Tascam vs PC, I am in the Bryston camp here. I have a BDP-1 (instead of a PC server) to play back my digital files and have not been disappointed with the sound quality. Their arguments re the use of linear power supplies and isolation from noise sources in a conventional computer make sense (speaking of RF Al). The Tascam uses similar techniques. Plus, the Benchmark tech actually confirmed that he prefers the Tascam/Benchmark combo vs a PC for those reasons.
Regarding the connections, the Benchmark has a word clock out and the Tascam has a corresponding word clock input. But you don't need them if you use AES/EBU. You have to set up the Tascam properly while the Benchmark is connected and powered on. Otherwise the Tascam will refuse the settings and tries to revert back to an internal clock.