All three of the VT100 models have both RCA and Balanced connections. As I remember there is a little switch. The mk1 version has reliability problems. The VT100 amps also difficult to bias. They also can't run KT120 tubes.
The VT series were not one of ARC's better efforts. I bought a used mk3 when I had to send my V70 in for service. I was very happy to get my V70 back. Though more detailed the VT100 mk3 sounded lifeless. I also had a mk2 in my system for a little while. I never directly compared them, but I think the mk2 is a little better sounding amp.
If the choice is between a VT100 (any version) and a Ref 75. The Ref 75 is a much better sounding amp. All of the Ref series amps are in a different league than the VT series.
Are there any interesting amps in your for sale used in your area? If so why not ask if you can hear them. Take a look at what else their system consists of. What preamp they are using. There is no substitute for experience. Listen to every thing you can so that you get a better frame of reference. I am good friends with my ARC dealer. I will sometime bring a piece home for the weekend just to hear it.