If you can bi-wire/bi-amp your center channel, that would be awesome. Otherwise, the 6th channel will not be used. Make sure that you don't have a signal into it if it's not hooked up to a speaker.
You will have to get a pre/pro with or without a tuner. If you are new at this, go with a more simple unit if possible. Get a remote that doesn't take a computer tech. I really like sunfire/sherbourne/anthem.
For zone 2: Most pre/pro's will run a second zone. However, using the same unit for this will make things more complicated. Plus, you will need remote IR emitters and such. If you are a novice, either use a completely separate second zone or pay a shop to set it up. I'd suggest selling your second amp and buying a multizone receiver like Denon 385.
You will have to get a pre/pro with or without a tuner. If you are new at this, go with a more simple unit if possible. Get a remote that doesn't take a computer tech. I really like sunfire/sherbourne/anthem.
For zone 2: Most pre/pro's will run a second zone. However, using the same unit for this will make things more complicated. Plus, you will need remote IR emitters and such. If you are a novice, either use a completely separate second zone or pay a shop to set it up. I'd suggest selling your second amp and buying a multizone receiver like Denon 385.