@ifanpayne - I'm no expert, however this is my opinion based on the information you have provided. The Qnap TS-251A is a NAS device - Network Attached Storage. It stores files that can be "seen" by anything on your network that has the appropriate credentials. If you are "seeing" the files from your Qnap on the Oppo BDP-105 Oppo Meida App, the files are probably being presented to your Oppo BDP-105 over a network connection (either ethernet or wireless wifi). If you are "seeing" the files now, I do not believe there would be any benefit to trying to connect it in a different manner.
If you wanted to try a physical connection from your Qnap device to the Oppo you would probably want to use a USB connection if you have USB on both the Qnap and the Oppo.
If you wanted to try a physical connection from your Qnap device to the Oppo you would probably want to use a USB connection if you have USB on both the Qnap and the Oppo.