The OP is clearly interested in accurate sound staging and imaging, as (at least) one goal of their set-up (considered two, by some).
While one can use test instruments, to measure and balance SPLs and correct frequency response aberrations; they can't replace the human ear, when it comes to ambience recovery and voice placement (whether instrument or vocal). What, exactly, would you measure, pray tell?
The scientifically designed tests and Chesky CD I mentioned, were created to allow one to use their ears and eliminate any variables, from their listening trials.