Just relax and enjoy the music.
Its a lot easier to obfuscate issues with a quick A/B comparison, than over the long term. That, "comfortable and relaxed...feeling", in YOUR listening room, over the long term, is ALL that's important.
Keep in mind: valves typically take something like 50 hrs of use, before they sound their best. Some will claim such is a result of ones ears adjusting.
This is a verbatim quote, from a letter Brent Jessee sends, whenever one buys valves from him:
"CARE AND FEEDING OF NEW TUBES: BREAK-IN
New tubes need a break-in period before they can fully exhibit their true sonic character when used in audio circuits. Preamp tubes especially benefit from a good break-in. This period may vary widely, but NOS vintage tubes usually need at least 48 hours of use, sometimes up to 100 hours. New current production tubes need 24-48 hours typically.
Good break-in can be accomplished by either leaving your tube unit turned on in a no-signal condition for 2 days, or you can just enjoy the tubes for several hours each evening and they will be broken in after several weeks. New tubes, especially NOS vintage tubes, may sound a bit edgy at first, but after the break-in period will mellow out and sound wonderful."
Enjoy your jams!