No, you’re not wrong. In fact, since you’re 80% HT I think getting a sub first makes a lot of sense. However...
I was considering getting a dedicated 2channel amp and use the receiver as the pre-amp for them.
NO!!!!! I forbid you from making this horrific mistake. Using the Denon as a pre will suck the life from your 2-channel performance, and your MLs deserve better than that. You’re better off getting an integrated amp so you bypass both the amp and preamp sections of the Denon. AVRs absolutely SUCK at 2-channel versus dedicated stereo components. Get something like this and you’ll be MUCH happier as will your MLs. Bryston plays very well with ML BTW. Best of luck.