I am cautiously optimistic that a separate DAC will sound better.
I doubt it… but I am not an optimist 😀
If you could describe what is lacking, or how it could be better then it can be easier to determine whether it might be better than the NODE 3.
My speakers do not have any room correction. Nor do they have XLR inputs. Sub 1 has XLR inputs. Sub 2 is connected via wireless transmitter which does not have XLR inputs.
I would suspect that REW and a UMIK might be worthwhile.
The DAC I have has a few PEQs that can be used for equalisation.
I could pretty easily believe that you could get a notable improvement by implementing some EQ without too much optimism. And particularly so in the bass.
I would suggest you avoid a DAC solely as a DAC, unless it also gives you some EQ options.
But I would also suggest you await some more learned suggestions.
If you had a stunningly good room, then maybe a different DAC would be better, or be different… but I do not know your room, nor your NODE 3, so it is at best just a guess.
Have you experimented with sub placement in your room?