The Fyne speakers are great, you CAN biamp them with 90db sensitivity that rotel should be "fine" to biamp. So:
Denon L-C-R pre outs to Rotel amp. Use a Y connector for L-R channels to biamp.
Denon amp driving the rest of the surrounds.
I would recommend the Martin Logan Forte amp for the speakers in the other room. No need to connect a source like the WIIM, it is also a streamer.
Before adding a dedicated dac/pre for two channel in your HT I would get all of the above sorted out first. Later you can do as Soix suggested, get a dedicated dac/pre amp for your two channel. I run mine that way and it works fine. But it gets confusing if you do everything at once. Get the amp sorted first. I think there are advantages using the rotel for biamping. I would not use different amps for your center, terrible idea. You want a seemless match for your front 3 channels.
This is the amp/streamer I recommend for the other room:
https://www.martinlogan.com/en/product/forte