I would highly recommend that you use AIFF instead of WAV in the iTunes environment. They are both uncompressed, but AIFF includes track information and album art in the file itself rather than putting it somewhere else.
This doesn't make a difference unless you have to do things like backup up file, move them to another machine or similar operations. Then you suddenly may have WAV files with no artist, album or track information. I have not been in that situation since I don't use WAV, but I have read plenty of stories of people who have had to re-rip their entire library (for me that would be a disaster, classical music requires manual edit since there is no consistency in the CDDB database).
You can always ask iTunes to convert your files to WAV (or MP3) in the future if that is needed for some reason, but AIFF is the best way of ensuring that you won't lose information (info or music bits) in the meantime.