iTunes is very easy to use and setup. The Airport Express can be a tad more difficult on a PC, but here is what I do:
Initial setup - use the Utility Wizard and setup the first AE as a Base Station when connected to either a ethernet network or a cable modem. Once you have done this, unplug the ethernet cable from the AE. Then to turn-on the wireless, go to your computer control panel and double-click on the wireless line in Network connections window. This will brign up a list of available wireless networks. If the apple network is not showing, go to "advanced" window. Then in this window you will see the Apple network displayed. Select it and hit "OK" button. Then, after a short time, the network will connect and you will see it displayed in the network connections window. Later you will see a pop-up display near the lower toolbar that has the IP address info, telling you that a new network has been detected.
Initial setup - use the Utility Wizard and setup the first AE as a Base Station when connected to either a ethernet network or a cable modem. Once you have done this, unplug the ethernet cable from the AE. Then to turn-on the wireless, go to your computer control panel and double-click on the wireless line in Network connections window. This will brign up a list of available wireless networks. If the apple network is not showing, go to "advanced" window. Then in this window you will see the Apple network displayed. Select it and hit "OK" button. Then, after a short time, the network will connect and you will see it displayed in the network connections window. Later you will see a pop-up display near the lower toolbar that has the IP address info, telling you that a new network has been detected.