For fun, do a little experiment, buy an inexpensive steel or brass outlet cover and install it in place of your plastic outlet covers. Plug in your system and listen.
You should notice a big change in sound.
WHY?
I will spit this out for discussion.
We cannot cure world hunger & explain every improvement we hear in audio as a direct result of decreasing capacitance and inductance while ensuring a low dielectric absorption. While this is important and the common angle to view how cables effect a system it is but a small piece of the puzzle.
Since everything resonates at certain frequencies, the wire (yes, the stuff inside our walls interconnects, and power cables) will resonate too. This is called (drum roll please...) Mechanical resonance. Mechanical resonance is particularly evident when energy is applied to something. Bang that drum again.... did you hear something?
While inductance and capacitance are very important in cable design and lets not forget dielectric.... Mechanical resonance is to a great degree what we hear when we hear differences in cables (and components). With power applied to the cable, it will resonate and thus emphasize certain frequencies, audibly changing the tonal quality you hear.
Cable geometry, and material used are key in producing neato sounding cables since they can effect the frequencies which resonate and those that don't. Different conductors will all resonate differently. For example: Copper resonates at 26.530MHz, Gold at 1.729MHz, Silver at 4.046MHz, and Platinum at 21.499MHz
The effects of the resonance of the material depends on the gauge of the wire and of course whether or not it is in contact with a sound deadening substance like Teflon - rubber - Shunyata Sand ... Virtual Dynamics Iron Powder or whatever. These substrates weight down the resonance to create the sonic signature.
Make sense?
Okay how about saying it like this:
Power coming into your house is already resonating - when you plug your cool aftermarket power cord into the wall, how do you think this could effect the sound? If the cable changes the existing mechanical resonance, it will change the way your system sounds.
So when you change your electrical outlet cover to a brass or steel cover and plug in your hefty power cord, you will hear a new mechanical resonance in your system and better understand as the topic of this thread reads -- WHY EXPENSIVE CABLES WHEN ROMEX BEHIND WALL... :)