I also agree with Bryan. Find the sweetspot for the speakers, and the correct toe-in first. You should have some basic room treatments, including side-wall reflection absorbers. Use a hand-mirror on the sidewalls to determine where to put them. 4" sonex works great, but its ugly. If you have WAF to deal with, then see the nice graphics you can get on the GIK acoustic panels.
Once you have these installed and the speakers located and toed-in properly (this can take months of trial and error, but worth it), then you might consider adding some 1/4 round ASC tubetraps near the rear insides of the speakers. Face the round surface inwards. These then can be "tuned" by moving them forward and backward along the inner line of the speaker walls. You can also rotate them slightly outwards to improve width of soundstage. These tubetraps in this configuration are not being used for bass, then are reflective in order to scatter unwanted backwave.
Finally, once you have these all done and it sounds pretty good and the image is focused (the source components must be really good for pinpoint imaging), then use Amarra EQ to dial-in the remaining bumps in the response. You will need a decent capacitor mic and a handheld spectrum analyzer. Then you will know where the bumps are and be able to input these to Amarra EQ and eliminate them. As long as you do 6-8dB of correction for each bump, this will sound good. Dont get carried away. Amarra EQ is extremely transparent and has 3 tunings for 3 bumps or rolls in the frequency response.
Room correction is less important than tuning the speakers in the room to get them as flat as possible.
Steve N.
Empirical Audio