Stehno, the 1st order crossover alignment, which consists of a single capacitor between drivers is a 90 degree phase alignment. It allows the bass driver to run full range, to its natural limits, and blocks the tweeter from operating below the frequency specified by the capacitor value. This protects the tweeter from harmful high power that may be present at the lower frequencies, and keeps intermodulation distortion to a minimum in the tweeter. The tweeter will be rolled-off at 6db/octave, from the crossover point downward, in this configuration.
The main advantage in this alignment, is that there is the fewest number of crossover parts to screw up the signal. And the presence of crossover inductors is eliminated, which is a major cause of phase shift. For this alignment to be successful, it requires careful matching of the drivers, so that there is not a "bump" in the response where the tweeter crosses in, and the woofer does not cross out. The woofer should be naturally rolling-off on its own at around 6db/octave, right at the crossover point, in order for this alignment to be optimal. Even though this is considered a 90 degree alignment, there is much to be said for the simplicity and signal preservation of this design. There are going to be phase-shifts in any crossover, and preserving the signal integrity is a valiant thing to do, considering the necessity of having a crossover in a multi-driver system. Having no crossover in a multi-driver system, with the drivers having matching natural roll-offs at a certain point would seem to be optimal, but the protection of the tweeter is vital, and intermod is present in unacceptably high amounts, as the tweeter vainly tries to respond to low frequency information that it cannot reproduce. So the single capacitor which functions primarily as a tweeter protector is a good compromise, if you can match the drivers well enough to keep the response curve smooth. If you want to avoid the crossover phase shift altogether, you must go to single-driver, which presents its own set of difficulties.