OK, Results of a little experiment I did:
I have ML Aerius i's and Kef Q65s. Just for the heck of it once I used the Kefs as my front L/R speakers and the ESL section of one Aerius i (with appropriate amplification) as my centre is a HT setup. The results were less than satisfying with well-recorded concert DVDs (Eric Clapton unplugged etc.) where I could clearly hear the 'difference in pace' between the Kefs and the Aurius i. The voice sounded unfocussed and muddy, more like hearing someone talking from behind! However, with movies this was less evident due to the ambience noises of surrounds.
Now, I may be way out on limb here with my assertion since Cinemas are obviously different to the ESL panel of Aerius i. Anyway, just make sure that you actually listen to it before making up your mind. Believe me, getting the ESL panel and Dynamic woofer integration is something even ML took years to master. So, more often than not, you might find this whole "mix and match" business frustrating.
Cheers,