Gordon: I am not very knowledgeable about the details, but I have a similar system as yours (two AppleTV's, one Airport Express) connected wirelessly to my iMac. I have about 450 gigs of Apple Lossless music stored on a 1 TB HD.
Most of the time I just listen to the lossless files directed directly to my various Apple "speakers' via iTunes. When I sit down to listen critically, I will use Pure Music and "broadcast" to my various locales using Airfoil. I understand that I am limited to standard "Red Book" CD specifications, but to my ears the Pure Music enhances space, detail, imaging and sense of presense. Others probably will disagree.
Give it a try. It is not expensive, and you may like it.
Most of the time I just listen to the lossless files directed directly to my various Apple "speakers' via iTunes. When I sit down to listen critically, I will use Pure Music and "broadcast" to my various locales using Airfoil. I understand that I am limited to standard "Red Book" CD specifications, but to my ears the Pure Music enhances space, detail, imaging and sense of presense. Others probably will disagree.
Give it a try. It is not expensive, and you may like it.