You think 172dB is double the volume of 85dB? You are kidding, right?
Maab, the ampunt of power delivered is determined by the input to the amp and the gain of the amp. The gain is basically how many times the amp multiplies the strength of the input signal. A 10W amp can have the same gain as a 1,000W amp, but the 10W amp will reach it's maximum limit and clip before the 1,000W one will.
If both amps have the same gain then they will produce the same volume with the same input. The differences are as Suarbrie pointed out and the headroom.