Rodman99999, the clipping of an amplifier does produce a square wave, and those 'corners' are where the odd harmonics reside.
If you compare a tube amp to a transistor amplifier when both are clipping, the much harder clip of the transistor amplifier is visible on any oscilloscope and the obviously higher quantity of odd-ordered harmonics is easy seen. This is why transistor amplifiers have a harsh overload character and also why most guitar players prefer the smooth overload of tube amplifiers.
If you compare a tube amp to a transistor amplifier when both are clipping, the much harder clip of the transistor amplifier is visible on any oscilloscope and the obviously higher quantity of odd-ordered harmonics is easy seen. This is why transistor amplifiers have a harsh overload character and also why most guitar players prefer the smooth overload of tube amplifiers.