tube recommendation please


I am brand new to tubes and need some advice. I have a PrimaLuna Prologue three which use two 5AR4, two 12AX7, and two 12au7. I listen to female vocal mainly, hopefully I can get bigger sound stage, and smooth and warm vocal.

I start off with the 12ax7 and ordered a pair of Tungsram produced in 1967. I am also planning to get a pair of 1960's Amperex, but I am waiting for some more reasonably priced.

My question is .. what should I get next? Should I upgrade the 5AR4 or the 12AU7 next? and is there any suggestion on those tubes?
gte357s
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Thanks, great explanation on the signal tube versus driver tube. I will double confirm that 12ax7 is the signal tube. I also read some comments saying the rectifier may not have any tonal impact. I just order a pair of CBS-Hytron 5814A (12au7) from eBay based on some comments on the internet. I think I am good now. I will wait for the tube and see how much difference does it make. If the result is positive, then I will spend more money and get some nicer 12ax7, like the Amperex long plate D getter =)
BTW, I got a question in buying tube. On eBay, there are many single tubes. But most of the time people would need a match pair. The test score provided seems to be different depends on the instrument used. So .. if I buy a single tube, would it be very difficult to find one that match? It seems those score reflects the life of the tube. If I got un-matched tubes, does it means one may die earlier than the other? Or it will affect the sound in a negative way?

Thanks in advance.
There is no best tube, only a best tube that will allow you to achieve the sound that you want. I would suggest living with the pre-amp for a while and then describe in detail what attributes you would like to improve. If you find that your current tube set up is too lush and warm you will get remarkably different tube suggestion if you had posted too dry and analytical.
Since you don't have a tester your better off buying matched pairs from one source not trying to match single tubes that have values from different testers.