I agree with Shadorne that the principal problem lies in your system's orientation along the long wall. I assumed, looking and your photos and overhead plan, that moving the system to the short wall was not an option. If that is an option, then that will be your best solution by far.
However, if you must keep your system on the long wall, then I respectfully disagree with Shadorne that your television is not a factor in your efforts to get the best sound possible with that configuration. I too have a large TV screen between my speakers. When I sit down to listen, I place a large piece of acoustic foam (12" in depth) in front of the TV screen. This minimizes undesirable comb filtering effects by reducing first order reflections from the TV. The result, IME, is an audible improvement in image focus and soundstage depth.
However, if you must keep your system on the long wall, then I respectfully disagree with Shadorne that your television is not a factor in your efforts to get the best sound possible with that configuration. I too have a large TV screen between my speakers. When I sit down to listen, I place a large piece of acoustic foam (12" in depth) in front of the TV screen. This minimizes undesirable comb filtering effects by reducing first order reflections from the TV. The result, IME, is an audible improvement in image focus and soundstage depth.