Both are excellent amplifiers, you really can't go wrong with a choice. I prefer the VAC to ARC, but it's really personal preference in the sound I like (I've always felt ARC was more tilted to the highs, even their newer models, and I like a full midrange, which I definitely get from the VAC). As far as tube-rolling, while you certainly can do it with the VAC, I haven't had the urge to do so, which is unusual for me.
One thing that Bifwynne points out is a definite consideration with the VAC, as it is very sensitive. I have a Shindo preamp with a lot of gain, and I could barely get the volume control to 7 o'clock before it was at a comfortable volume. I actually have put in attenuators at the amp (something that is built in to VAC's Phi 300.1) to get a little more play in the Shindo volume control. On the other hand, using a TVC passive (Promethius) as my preamp has resulted in no such problems, so you may need to consider the output from your preamp in making your choice.