Biwiring is explained scientifically on the Vandersteen website
A theory is proposed...low frequency high power signals induce noise on high frequency low power signals. It is hardly science though.
Given the low impedances of speaker loads and amplifier outputs it seems unlikely that noise can be induced in speaker wires that would be at all audible.
Of course, there is some ground truth, if you run unshielded line level signal wires next to some AC power cables feeding an airconditioner then it is quite likely you will pick up some noise...but this is because of the very low levels of signal at line level and the fact that termination impedances are around 10K Ohm - meaning that tiny stray induced currents may actually produce audible noise - even allowing you to pick up interference from a radio station or a ham radio perhaps..
A more logical explanation for reported observations may be caused by unecessarily wide bandwidth amplifiers of the sort that amplify flat up to 200 KHz - instabilities in amps of this type (with large amounts of feedback) might be affected by the slight change in cable inductance that biwiring would bring versus a conventional speaker wire. (Why anyone needs an amp flat to 200 KHz for audio reproduction is rather bewildering, however, specifications like this might make a buyer think the amp is "better" than one which rolls off above 20 KHZ - so they sell - the same way that damping factors of 1000 sell...)