Well, two things to consider. One is the source for the music as the iPod and the other being the more powerful amp. 95 watts with 92 dB sensativity speakers is plenty of power. I play my 89 dB speakers with a 100 watt amp and I can rock out pretty well. More power is usually a good thing, but in your case, I think any extra cash should be on the source, not the amp.
in general, an uncompressed digital source will sound best, and, you want your source device (iPod in your case) to output a fully digital signal so that the DAC in the Peachtree amp can process the signal rather than the rinky dink DAC in the iPod. Unfortunately the iPod will not output a digital signal on its own. You can't connect it via USB to the Peachtree without a special dock that can extract a pure digital signal from the iPod, which are available.
my advice is to go another way. Skip the CD player. Rip your CDs at an uncompressed setting on a computer, sell the CD collection and sell any CD player you have. Use the iPod for your car and walking around.
now you have to get the music from the computer hard drive and iTunes to the Peachtree. To do this you will need s streaming device. Look into Bluesound node, Sonos connect, Apple TV. All will handle regular resolution uncompressed cd files, but only the Bluesound node will handle high resolution music if you get into that down the road. I also recommend experimenting with Tidal HiFi. At $15 per month it is more expensive than Apple Music, but it streams all of the music at uncompressed cd quality, which iTunes and the others do not. If you have the budget for a Bluesound node or node 2 and a network connected hard drive, you are really set up nicely. You'll have your own collection and 4 million CDs in the form of a Tidal HiFi subscription.
let me know if you have any other questions as of course there are several ways to configure a setup like this. You could skip the Bluesound node altogether and use a computer if that is convenient.