Here is an option that is very simple to use 4 channels of the Rotel.
(Example only, quality should be same as interconnects used.) Use this type of Y adapter on each (L&R) of the SR5006’s main pre-outs.
https://www.amazon.com/Hosa-YRA-104-Dual-RCAF-Y-Cable/dp/B000068O4Y/ref=sr_1_2?s=electronics&ie=UTF8&qid=1465579594&sr=1-2&keywords=rca+y+adapter
This gives you 2 pair of stereo RCA outputs with a female connection. That way, you can use normal interconnects for everything. (The splitter box from the link in your post would work also, just using 2 of its 4 outputs.) Use one of the pairs for 2 channels on the Rotel to the SS6 like the current setup. Then connect the other pair to the input of a passive volume control,
cheap passive VC -
https://www.amazon.com/Axxess-AALC-Controller-Discontinued-Manufacturer/dp/B003FPD3IS/ref=pd_sim_107...
better passive VC - only one input would be used
http://schiit.com/products/sys
with the passive VC output driving 2 more channels of the Rotel to the outdoor speakers. Indoor speakers will play as they do now, but outdoor speakers will be able to play louder due to the increase in available power not being connected to the SS6. The main volume on the SR5006 will still affect all speakers, but the passive VC on the outdoor speakers can be turned down or completely off allowing a desired volume inside. Keep in mind that the passive VC only attenuates, so maximum volume of outdoors will still be determined by the SR5006 volume control. No doubt the outdoor speakers will be able to play as loud or louder than they do now with a given indoor volume, but more important, this solves the problem to turn outdoor down or off.
Now to try and use that 5th channel on the Rotel gets a little more complex. You would need the splitter box from your link, 2 passive VC’s, and a stereo to mono converter like this,
http://www.mcmelectronics.com/product/MONACOR-SMC-1-/50-9042
I do not advise using a simple Y adapter to convert stereo to mono. See previous post.
I would definitely use 4 channels of the Rotel as this creates more flexibility between indoor and outdoor speakers, but not sure about trying to use that 5th channel. Is there a major problem with volumes between the indoor speakers? Something too loud, not loud enough? And if so, what?