Hi Gnerator:
Yes, you are overthinking it. :) These are probably PS
de-coupling caps, and size and heat resistance are most likely the
dominant factors.
The location matters. It is quite possible that those caps are exposed to unusually high heat. The temperature in an amp isn't the same at every point, it is quite possible the caps are in a particularly bad hot spot. Also possible that the manufacturer of the originals was too optimistic re: heat / failure rates. ML seems to have learned something and chosen to act proactively.
Second, it's not just about thermal stability it is about failure. Caps with higher thermal ratings last longer.
Esoteric caps are huge by comparison to their "normal" counterparts, AND honest to god, it's quite probable that in this application they make no difference at all.
Best,
E