I agree with mhart032 - you are unlikely to improve on the DAC in the Marantz AVR without spending a good deal more. I haven't heard the Emotiva amp, except at a show, but I have listened a bit to some mid-priced Revel speakers. I liked them, but I would not catagorize them as particularly warm. If you are looking for a warmer sound, I would focus on the amp and speakers. The Marantz AVRs I have heard are also just to the warm side of neutral. For an amp, at least for the front channels, consider Odyssey Audio. I have an HT3 3-channel amp for my front channels, and it is as warm as I would want without losing any detail or extension in the mids and highs. It was noticeably warmer and smoother sounnding than the Rotel amp it replaced, and an AVA amp I also auditioned at home. I know this may be more than you want to spend, but a call to Odyssey might be worthwhile.
And don't ignore the cables and power. Better cables and better quality, cleaner power can make a system sound warmer by reducing RFI and other powerline hash, which, I believe, people hear as etch and grain in the treble.