While lots of people pooh pooh optical cables, they are ideal for PC outputs as they utterly reject ground loops as well as EMI/RFI noise.
One hidden issue in digital transmission is ground loops which can and do occur and seem to increase jitter levels so high that it causes audible degradation. In an ideal world, all DAC's are isolated from this but not all are. This is also made much worse with switching power supplies like a laptop's wall wart or PC. Sadly, DAC's do not have any indicator of this. There's no light that says "ground loop" or "excessive jitter" and honestly I'd feel a little comforted if they did.
There's no reason to believe that any coaxial cable would be better than any other at reducing ground loops though, my comment was just about how and why Optical can be far superior.
Best,
E